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For such issues the tables provide both current yields and yields to earliest redemption and thus reveal the speculative choices offered to the investor For ascertaining the going rate of long-term interest, new issues or seasoned issues selling at around 100 and not redeemable are far more reliable than high-premium issues The year 1819 was marked by an industrial and commercial crisis which had little adverse effect on the bond market Three small loans floated in 1820 1821, principally to permit the continued redemption of high rate war loans, provide an interesting clue to investor preference in a rising bond market These were: 1820 $10 million 1820 $20 million 1821 $47 million 5s of 1820, redeemable in 1832; sold at 100 = 5% 6s of 1820, redeemable at pleasure of United States; sold at 102 = 588%.

reactions have been adapted for synthesis of other conjugated polyaromatic polymers, for example, poly uorenes (LVII).

2-14j-3 Poly(p-phenylene Vinylene) Poly(p-phenylene vinylene) [IUPAC: poly(1,4-phenyleneethene-1,2-diyl)] (PPV) (LVIII) is obtained by the sequence in Eq. 2-230 involving successive base- and heat-induced

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It is true my house is so stuffed with instruments that every catastrophe sounds musical. But because of this close association with worldwide instruments, experimental and non, I can tell you something with complete certainty: Circuit-bending takes you to a new place. Persons excited by the history of musical instruments appreciate that the clear illogic of chance electronics is somewhat groundbreaking. And the extra-musical implications of invention and sociology are interesting, too. But what s truly fascinating is that anyone at all now can, in an easy evening s work, discover and build a unique instrument capable of making sounds and music outside systems of human presumption, music that no one else has yet heard or even dreamed of.

5s of 1821, redeemable in 1835; sold at 1051 8 = 450%, and at 108 = 425%..

2-230

eliminations of dialkyl sul de and hydrogen halide [Cho, 2002; Kraft et al., 1998; Lenz et al., 1988; van Breemen et al., 2001]. PPV can also be synthesized by the Heck coupling of aryl halides with alkenes (Eq. 2-231).

2-231

The yield was highest for the issue with early redemption risk and much lower for those with later redemption risks. In 1824 1825 the market reached its high prices for this decade. The Treasury then undertook a refunding to reduce the interest charges on

The corresponding azomethine polymers (LIX) have been synthesized by the reaction of the appropriate diamine and dialdehyde [Farcas and Grigoras, 2001; Gutch et al., 2001; Morgan et al., 1987].

he 1960s was a clothing optional decade. What to do with all that bare flesh Perfume it, sunbathe it, paint it, electrify it!

2-15

The drive for heat-resistant polymers has led to an exploration of polymers based on inorganic elements since bond energy considerations indicate that such polymers should be superior to organic polymers in thermal stability [Allcock et al., 2003; Archer, 2001; Manners, 1996; Nguyen et al., 1999; Ray, 1978]. Both inorganic and organometallic polymers have been studied. Inorganic polymers are polymers containing no organic groups, while organometallic polymers contain a combination of inorganic and organic groups. Inorganic and organometallic polymers would have potential for a variety of uses as partial or complete substitutes for organic bers, elastomers, and plastics where ame and heat resistance are important; as marine antifoulants, bactericides, medicinals, fungicides, adhesives, photoresists, photosensitizers, photostabilizers; and as conducting polymers. in general much of this potential is unrealized, although signi cant exceptions exist the polysiloxanes (Secs. 2-12f and 7-11a), poly(p-phenylene sul de) (Sec. 2-14d), polyphosphazenes (Sec. 7-11b), and polysilanes (Sec. 2-15b-3) are commercial polymers. 2-15a Inorganic Polymers

the war debt This was in the form of three 41 2% issues which may be combined as follows: 1824 1825 $145 million 41 2s of 1824, redeemable in 1832 1834; at 100 = 450% This was the last long-term financing until 1841 The problem of the government now was how to disburse its surplus From 1825 through 1829 the bond market declined moderately Something like 41 2% seemed like a going rate for bonds with an early redemption risk By 1835 the debt was entirely paid off During the years from 1810 to 1829 the current yields on bonds of the State of Massachusetts and of the City of Boston, also given in Table 51, fluctuated far less than the yields on federal government securities.

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