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The synthesis of high-molecular-weight inorganic polymers is more dif cult than that of organic polymers. Chain polymerization through multiple bonds is routinely used for organic monomers such as ethylene. This route is not readily available for inorganic polymers because monomers with multiple bonds between inorganic elements are generally unstable. Chain polymerization of cyclic monomers (ring-opening polymerization) offers more promise and is discussed in Chap. 7. Step polymerization using monomers with two different functional groups, relatively easy to accomplish with organic molecules, is more dif cult for synthesizing inorganic polymers. The chemistry of inorganic functional groups is not well understood, and monomers of high purity are dif cult to prepare. Thus, it is dif cult to achieve the polymer molecular weights needed to obtain materials with suf cient mechanical strength for fabrication into plastic, elastomers, and bers. With almost no exceptions attempts to synthesize inorganic polymers that can directly substitute for organic polymers have been unsuccessful. Although the intrinsic thermal stability is often good, a variety of dif culties must be overcome before a usable polymer is obtained. Inorganic polymers typically suffer from various combinations of poor hydrolytic stability, low polymer molecular weights, and low chain exibility. For example, inorganic polymers with high molecular weights and good hydrolytic stability are often highly in exible. A large de ciency for many polymers is their intractability to current techniques of fabricating polymers into products such as lm, ber, tubing, and other objects. This does not mean that inorganic polymers are useless. Inorganic polymers comprise many of the materials that are employed at home, industry, and elsewhere. Let us brie y consider some of those materials. [Several wholly inorganic polymers, polysulfur, polyselenium, polythiazyl, and poly(dichlorophosphazene), are discussed in Chap. 7.] 2-15a-1 Minerals

A variety of mineral-type materials are inorganic polymers [Ray, 1978]. Silica [(SiO2)n] is found in nature in various crystalline forms, including sand, quartz, and agate. The various crystalline forms of silica consist of three-dimensional, highly crosslinked polymer chains composed of SiO4 tetrahedra where each oxygen atom is bonded to two silicon atoms and each silicon atoms is bonded to four oxygen atoms. Silicates, found in most clay, rocks, and

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Since these local issues had 5% nominal rates and in the decade 1820 1829 commanded premiums, their yields were probably kept up by fear of redemption But in the lower markets of 1810 1819 discounts were usual, and these provided a true yield that was always far below the yield on Treasury 6s and sometimes below the yield on Treasury 3s Allowing for distortions due to rate differences and premiums, it seems that Massachusetts bonds suffered from the War of 1812 far less than treasury bonds and recovered less with peace The yield and price differences were not very large in the 1820 s, suggesting that the popularity of the national government securities may by then have approximated that of Massachusetts and the City of Boston securities 1830 1859.

And that s what we did. You see, the bent mini amp s body contacts, when bridged by a person s fingers, would make the instrument respond as an electronic oscillator. Varying the pressure of finger contact would tune the oscillator in the same way that turning the pitch dial on an oscillator would, from super low to ultra high. But what was even more interesting was that the electricity could be passed through many people at one time. Clad or semi-clad, we d have people hold hands, persons at each end of the human chain touching a body-contact, thereby placing everyone within the live circuit. The bent mini amp would respond with a loud, sustained pitch as long as nobody moved. Whichever persons broke the chain could then play each others bodies, because various body parts sounded different depending on the completeness of contact. A bare arm, for example, made a good contact and resulted in a pure tone, whereas a hairy arm made poorer contact and resulted in a scratchy tone. Moisture made for nice contacts. Kissing even better. So there was a lot of hugging, smooching, slurping, and worse, all to the tune of an oscillator gone wild as we gyrated around the floor, holding onto each others whatever. Sure, this was art. But was it music

soils, are also based on SiO4 tetrahedra. However, they differ from silica in having Si : O ratios under 1 : 2 (compared to 1 : 2 for silica) and contain Si groups with associated O metal cations. Single-strand, double-strand (ladder), sheet (composed of multiple-doublestrand sheets analogous to graphite), and three-dimensional polymer chains occur depending on the Si : O ratio, cation : Si ratio, and charge on the cation. Talc contains magnesium and possesses a sheet silicate structure. Tremolite, an asbestos mineral, has a double-strand structure and contains calcium and magnesium. The silicates, similar to silica itself, are highly rigid materials because of their ladder, sheet, and three-dimensional structure. Even the single-strand chains are rigid since the cations act to hold together adjacent polymer chains. 2-15a-2 Glasses

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